Oxygen reduction on anodically formed titanium dioxide

被引：88

作者：

Mentus, SV ^{[1
]}

机构：

[1] Univ Belgrade, Fac Phys Chem, YU-11000 Belgrade, Serbia And Mont, Serbia

来源：

ELECTROCHIMICA ACTA | 2004年 / 50卷 / 01期

关键词：

oxygen reduction reaction; reaction path; rotating disk electrode; titanium dioxide; voltammetry;

D O I：

10.1016/j.electacta.2004.07.009

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Oxygen reduction on anodically formed TiO2 was studied in both alkaline and acidic water solutions, using dc voltammetry combined with the rotating disk technique. The possible interference with hydrogen evolution reaction was considered. By means of Levich-Koutecky plot, in alkaline media, 4e(-) reduction path was confirmed, while with the transition to acidic media, the rising participation of the indirect, 2e(-) reduction path was evidenced. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：27 / 32

页数：6

共 38 条

[31] The reduction of oxygen on Pt-TiO2 coated Ti electrodes in alkaline solution [J].

Tammeveski, K ;

Tenno, T ;

Rosental, A ;

Talonen, P ;

Johansson, LS ;

Niinistö, L .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :669-676

[32]

TARASEVICH MR, 1983, COMPR TREAT, pCH6

[33] HYDROGEN EVOLUTION REACTION ON ANODIC TITANIUM-OXIDE FILMS [J].

TORRESI, RM ;

CAMARA, OR ;

DEPAULI, CP ;

GIORDANO, MC .

ELECTROCHIMICA ACTA, 1987, 32 (09) :1291-1301

[34] INFLUENCE OF THE HYDROGEN EVOLUTION REACTION ON THE ANODIC TITANIUM-OXIDE FILM PROPERTIES [J].

TORRESI, RM ;

CAMARA, OR ;

DEPAULI, CP .

ELECTROCHIMICA ACTA, 1987, 32 (09) :1357-1363

[35]

Trasatti S, 1999, INTERFACIAL ELECTROCHEMISTRY, P769

[36]

Tsujiko A, 2002, J PHYS CHEM B, V106, P5878, DOI 10.1021/jp0121441

[37] Structure and energetics of water adsorbed at TiO2 anatase (101) and (001) surfaces [J].

Vittadini, A ;

Selloni, A ;

Rotzinger, FP ;

Gratzel, M .

PHYSICAL REVIEW LETTERS, 1998, 81 (14) :2954-2957

[38] ELECTROREDUCTION OF OXYGEN - NEW MECHANISTIC CRITERION [J].

WROBLOWA, HS ;

PAN, YC ;

RAZUMNEY, G .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1976, 69 (02) :195-201

← 1 2 3 4 →