Aryl Phosphoramides: Useful Electrophiles for Suzuki-Miyaura Coupling Catalyzed by a NiCl2/dppp System (dppp=1,3-Bis(diphenylphosphino)propane)

被引：51

作者：

Zhao, Yu-Long ^{[1
,2
]}

Li, You ^{[2
]}

Li, Yu ^{[1
]}

Gao, Lian-Xun ^{[1
]}

Han, Fu-She ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China

[2] NE Normal Univ, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 17期

关键词：

biaryls; nickel; phenols; phosphane ligands; Suzuki-Miyaura coupling; ALKENYL PHOSPHATES; ARENESULFONATES; ACTIVATION; TOSYLATES; AMINATION; ETHERS; BOND; HYDROXYLAMINES; CHLORIDES; BROMIDES;

D O I：

10.1002/chem.201000420

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation presantation Suzuki-Miyaura coupling: We disclose a new strategy for phenol activation in the first Suzuki-Miyaura coupling of phenol derivatives activated by forming aryl bis(2-oxo-3-oxazolidinyl)phosphines as a highly efficient and broadly applicable methodology for the diverse synthesis of biaryls and heterobiaryls (see scheme). The use of readily available, stable NiCl2/dppp as the catalyst system also provides an important advance. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4991 / 4994

页数：4

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