Enhanced bonding of poly(ethylene-co-acrylic acid) to oxides through surface-bound alkoxyzirconium complex interfaces

被引：25

作者：

VanderKam, SK ^{[1
]}

Bocarsly, AB ^{[1
]}

Schwartz, J ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 03期

关键词：

D O I：

10.1021/cm970637q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface-bound alkoxyzirconium complexes form stable interfaces between poly(ethylene-co-acrylic) acids and various substrates. These interfaces enhance polymer bonding to the oxide surface as demonstrated by stability to washing. Both 5% by weight and 15% by weight acrylic acid copolymers were deposited onto modified and unmodified oxidized aluminum, iron, porous silicon, and indium tin oxide, and both polymers exhibited increased surface loading onto the alkoxyzirconium-modified surface when compared with the untreated substrate.

引用

页码：685 / +

页数：4

共 16 条

[1] Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals [J].