Preparation of cyclohexene-d10 by H/D-exchange reaction

被引：19

作者：

Ishibashi, Kenichi ^{[1
]}

Matsubara, Seijiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 06期

关键词：

D O I：

10.1246/cl.2007.724

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Preparation of fully deuterium-labeled cyclohexene by H/ D-exchange reaction was performed efficiently in the presence of ruthenium catalyst under irradiation of microwaves. The reaction proceeds via a repetition of hydroruthenation and beta-elimination.

引用

页码：724 / 725

页数：2

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