Crystalline VO2 (B) nanorods with a rectangular cross-section

被引：32

作者：

Chen, Zhanjun ^{[1
,2
]}

Gao, Shaokang ^{[1
,2
]}

Jiang, Lilong ^{[1
]}

Wei, Mingdeng ^{[1
,3
]}

Wei, Kemei ^{[3
]}

机构：

[1] Fuzhou Univ, Inst New Energy Technol & Nanomat, Fuzhou 350002, Fujian, Peoples R China

[2] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Fujian, Peoples R China

[3] Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2010年 / 121卷 / 1-2期

关键词：

VO2 (B); Nanorod; Rectangular cross-section; Hydrothermal; Electrochemical properties; HYDROTHERMAL SYNTHESIS; VANADIUM DIOXIDE; ELECTROCHEMICAL PROPERTIES; NANOFIBERS; NANOWIRES; NANOBELTS; ROUTE;

D O I：

10.1016/j.matchemphys.2010.01.032

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this study, VO2 (B) nanorods were successfully synthesized using a simple hydrothermal route, in which templates or catalysts were absent. The synthesized VO2 (B) nanorods are highly crystalline and have a rectangular cross-section. Following this, a possible model, reacting-exfoliating-recrystallizing, was proposed for the formation of VO2 (B) nanorods. A lithium battery using VO2 (B) nanorods as the active material of the positive electrode exhibits a high initial discharge capacity of 605 mAh g(-1), revealing the formation of Li1.82VO2. Such a high degree of electrochemical performance is attributed to the intrinsic properties of crystalline VO2 (B) nanorods. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：254 / 258

页数：5

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