A nanoporous Ag(I)-MOF showing unique selective adsorption of benzene among its organic analogues

被引：75

作者：

Cheng, Jun-Yan ^{[1
]}

Wang, Peng ^{[1
,2
]}

Ma, Jian-Ping ^{[1
]}

Liu, Qi-Kui ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Peoples R China

[2] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 89期

关键词：

SCHIFF-BASE LIGANDS; FRAMEWORKS; SEPARATION; HYDROCARBONS; SITES;

D O I：

10.1039/c4cc03204g

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A stable porous Ag(I)-MOF with new topology is constructed from AgSbF6 and 3,6-bis[2-(4-oxide-quinoxaline)-yl]-4,5-diaza-3,5-octadiene (L). This compound can be a highly selective porous MOF material to effectively separate benzene from its six-membered cyclic organic analogues such as cyclohexane, cyclohexene and o-, m-, p-xylene under ambient conditions in both vapor and liquid phases.

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收藏

页码：13672 / 13675

页数：4

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