Stabilization of perovskite phase and enhancement in dielectric properties by substitution of Pb(Mg1/3Nb2/3)O3 to Pb(Zn1/3Ta2/3)O3

被引:38
作者
Chae, MC [1 ]
Lim, SM [1 ]
Kim, NK [1 ]
机构
[1] Kyungpook Natl Univ, Dept Inorgan Mat Engn, Taegu 702701, South Korea
基金
新加坡国家研究基金会;
关键词
B-site precursor method; Pb(Mg1/3Nb2/3)O-3(PMN); Pb(Zn1/3Ta2/3)O-3(PZT); dielectric constant; Curie temperature; diffuseness;
D O I
10.1080/00150190008228399
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Stabilization of a perovskite structure in the Pb(Zn1/3Ta2/3)O-3-Pb(Mg1/3Nb2/3)O-3 system was attempted. System powders were prepared by reacting PbO and pre-synthesized B-site precursor compositions. Perovskite phase developments were studied as functions of substituent amounts and heat-treatment stages. Formation tendencies of perovskite/pyrochlore structures were discussed in terms of electronegativity difference and tolerance factor. Dielectric properties of the system ceramics were investigated, with further analyses on diffuseness characteristics in the dielectric constant spectra.
引用
收藏
页码:25 / 35
页数:11
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