Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology

被引:83
作者
Chun, Hyungphil [1 ]
Moon, Jumi [1 ]
机构
[1] Hanyang Univ, Coll Sci & Technol, Dept Appl Chem, Ansan 426791, South Korea
关键词
D O I
10.1021/ic070036t
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A topological isomer based on Zn-2 paddlewheel, dicarboxylate, and diamine ligands is synthesized by solvothermal methods after careful modulation of the reaction conditions. The new framework is characterized by a pillared Kagome net topology and possesses a sustainable pore structure with high surface area (similar to 2400 m(2)/g) and large hexagonal channels (similar to 15 angstrom).
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页码:4371 / 4373
页数:3
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