Bioinspired polymer vesicles based on hydrophilically modified polybutadienes

被引：84

作者：

Hordyjewicz-Baran, Zofia ^{[1
]}

You, Liangchen ^{[1
]}

Smarsly, Bernd ^{[1
]}

Sigel, Reinhard ^{[1
]}

Schlaad, Helmut ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces Colloids Ch, D-14424 Potsdam, Germany

来源：

MACROMOLECULES | 2007年 / 40卷 / 11期

关键词：

D O I：

10.1021/ma070347n

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Four polymeric amphiphiles and biohybrids were produced by free-radical additions of w-functional mercaptans onto a I,2-polybutadiene with a number-average of 40 repeat units. Flocculation or precipitation of polymer was recognized by a steep increase of turbidity and scattering intensity. The results show that the polymer redispersed upon addition of 0.1 N NaOH. The scattering intensity was the same as at the beginning of the titration cycle, indicating that the process was fully reversible. Small-angle X-ray scattering (SAXS) indicated the presence of vesicles in 5 wt % solutions of 1-3. Because of the similarity to liposomes, the biohybrid systems in particular could readily be used as model membranes to study biological recognition processes or for biomedical applications.

引用

页码：3901 / 3903

页数：3

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