Preparation of porous flower-shaped SnO2 nanostructures and their gas-sensing property

被引:137
作者
Huang, Jiarui [1 ,2 ]
Yu, Kun [1 ]
Gu, Cuiping [1 ]
Zhai, Muheng [1 ]
Wu, Youjie [1 ]
Yang, Min [1 ]
Liu, Jinhuai [2 ]
机构
[1] Anhui Normal Univ, Coll Chem & Mat Sci, Anhui Key Lab Funct Mol Solids, Wuhu 241000, Peoples R China
[2] Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2010年 / 147卷 / 02期
关键词
Tin oxide; Flower-like; Nanostructures; Porous; Gas sensor; FACILE SYNTHESIS; OXIDE NANOTUBES; INDIUM SULFIDE; GRAIN-SIZE; SENSITIVITY; FABRICATION; GROWTH; CONVERSION; TEMPLATES; SPHERES;
D O I
10.1016/j.snb.2010.03.085
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Porous flower-like tin oxide (SnO2) nanostructure is prepared by annealing of the flower-like tin sulfur (SnS2) nanostructures. The morphology and crystal structure of the flower-like SnO2 nanostructures are characterized by field emission scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The average SnO2 crystallite size is about 6.1 nm. The as-prepared porous flower-like SnO2 nanostructures exhibit a good response and reversibility to some organic gases, such as ethanol and n-butanol. The sensor responses to 100 ppm ethanol and n-butanol are 42.6 and 77.2, respectively, at a working temperature of 240 degrees C. In addition, the sensors exhibit a good response to methanol, 2-propanol. and acetone. The relationship between the gas-sensing properties and the microstructure of the as-prepared flower-like SnO2 nanostructures is also investigated. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:467 / 474
页数:8
相关论文
共 39 条
[21]   Highly sensitive and fast-responding SnO2 sensor fabricated by combustion chemical vapor deposition [J].
Liu, Y ;
Koep, E ;
Liu, ML .
CHEMISTRY OF MATERIALS, 2005, 17 (15) :3997-4000
[22]   Nonaqueous synthesis of nanocrystalline semiconducting metal oxides for gas sensing [J].
Pinna, N ;
Neri, G ;
Antonietti, M ;
Niederberger, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (33) :4345-4349
[23]   The template-free synthesis of square-shaped SnO2 nanowires:: the temperature effect and acetone gas sensors [J].
Qin, Lipeng ;
Xu, Jiaqiang ;
Dong, Xiaowen ;
Pan, Qingyi ;
Cheng, Zhixuan ;
Xiang, Qun ;
Li, Feng .
NANOTECHNOLOGY, 2008, 19 (18)
[24]   The effect of grain size on the sensitivity of nanocrystalline metal-oxide gas sensors [J].
Rothschild, A ;
Komem, Y .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (11) :6374-6380
[25]   Hydrothermal growth and gas sensing property of flower-shaped SnS2 nanostructures [J].
Shi, Weidong ;
Huo, Lihua ;
Wang, Haishui ;
Zhang, Hongjie ;
Yang, Jianhui ;
Wei, Pinghui .
NANOTECHNOLOGY, 2006, 17 (12) :2918-2924
[26]   Direct growth of mono- and multilayer nanostructured porous films on curved surfaces and their application as gas sensors [J].
Sun, FQ ;
Cai, WP ;
Li, Y ;
Jia, LC ;
Lu, F .
ADVANCED MATERIALS, 2005, 17 (23) :2872-+
[27]   Fast-response and high sensitivity gas sensors based on SnO2 hollow spheres [J].
Tan, Yu ;
Li, Chengchao ;
Wang, Yong ;
Tang, Jianfeng ;
Ouyang, Xicheng .
THIN SOLID FILMS, 2008, 516 (21) :7840-7843
[28]   Fabrication of a SnO2 nanowire gas sensor and sensor performance for hydrogen [J].
Wang, B. ;
Zhu, L. F. ;
Yang, Y. H. ;
Xu, N. S. ;
Yang, G. W. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (17) :6643-6647
[29]   Highly sensitive gas sensors based on hollow SnO2 spheres prepared by carbon sphere template method [J].
Wang, Caihong ;
Chu Xiangfeng ;
Wu Mingmei .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 120 (02) :508-513
[30]  
Wang CM, 2008, CHINESE J STRUC CHEM, V27, P445