Straight-chain alkanes template the assembly of water-soluble nano-capsules

被引：69

作者：

Gibb, Corinne L. D. ^{[1
]}

Gibb, Bruce C. ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 16期

关键词：

D O I：

10.1039/b618731e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cavitand 1 is sufficiently predisposed to form nano-scale capsules in the presence of templating straight-chain hydrocarbons; quaternary complexes are formed when two copies of smaller guests are encapsulated, whilst larger guests form ternary entities.

引用

页码：1635 / 1637

页数：3

共 25 条

[1] Encapsulation and stabilization of reactive aromatic diazonium ions and the tropylium ion within a supramolecular host [J].

Brumaghim, JL ;

Michels, M ;

Pagliero, D ;

Raymond, KN .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (24) :5115-5118

[2] Hydrophobicity: Two faces of water [J].

Chandler, D .

NATURE, 2002, 417 (6888) :491-491

[3] Chemistry -: Amplification by compartmentalization [J].

Chen, J ;

Körner, S ;

Craig, SL ;

Rudkevich, DM ;

Rebek, J .

NATURE, 2002, 415 (6870) :385-386

[4] Supramolecular assembly dynamics [J].

Davis, AV ;

Yeh, RM ;

Raymond, KN .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4793-4796

[5] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[6]

GIBB BC, 2003, J SUPRAMOL CHEM, P123

[7] Well-defined, organic nanoenvironments in water: The hydrophobic effect drives a capsular assembly [J].

Gibb, CLD ;

Gibb, BC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11408-11409

[8] Templated assembly of water-soluble nano-capsules: Inter-phase sequestration, storage, and separation of hydrocarbon gases [J].

Gibb, Corinne L. D. ;

Gibb, Bruce C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16498-16499

[9] Photo-Fries reaction in water made selective with a capsule [J].

Kaanumalle, Lakshmi S. ;

Gibb, Corinne L. D. ;

Gibb, Bruce C. ;

Ramamurthy, V. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2007, 5 (02) :236-238

[10] A hydrophobic nanocapsule controls the photophysics of aromatic molecules by suppressing their favored solution pathways [J].

Kaanumalle, LS ;

Gibb, CLD ;

Gibb, BC ;

Ramamurthy, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) :3674-3675

← 1 2 3 →