Catalysts based on palladium dendrimers

被引：147

作者：

Andres, Roman ^{[1
]}

de Jesus, Ernesto ^{[1
]}

Carlos Flores, Juan ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Inorgan, Madrid 28871, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2007年 / 31卷 / 07期

关键词：

D O I：

10.1039/b615761k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report reviews the role of palladium dendrimers in catalysis as (a) soluble macromolecules for the support of catalysts, that are separable by nanofiltration techniques; (b) ligand-modifiers that can create specific metal nanoenvironments and tune the solubility of the catalyst; (c) spacers for the support of molecular catalysts that can proportionate a more homogeneous-like environment to the supported catalytic sites; and (d) precursors for the synthesis of mono- and bimetallic nanoparticles of controlled size and narrow size distribution. Some examples of catalysis with related metal systems, such as star-shaped molecules or hyperbranched polymers, are also given.

引用

页码：1161 / 1191

页数：31

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