A porous chiral framework of coordinated 1,3,5-benzenetricarboxylate: quadruple interpenetration of the (10,3)-a network

被引:216
作者
Kepert, CJ [1 ]
Rosseinsky, MJ [1 ]
机构
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
关键词
D O I
10.1039/a705336c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chiral and porous cubic coordination polymer Ni-3(btc)(2)(py)(6)(eg)(6).xeg.yH(2)O (btc = 1,3,5-benzenetricarboxylate, py = pyridine, eg = ethylene glycol, x approximate to 3, y approximate to 4) is based on the interpenetration of four independent (10,3)-a networks, and contains large interconnected cavities with diameter 16 Angstrom which may be desolvated without irreversibly destroying the porous framework structure.
引用
收藏
页码:31 / 32
页数:2
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