Phthalocyanines - Versatile components of molecular conductors

被引：258

作者：

Inabe, T ^{[1
]}

Tajima, H

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr030649x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pc-based conductors with clearly defined structures were evaluated. When planar Pc complexes were the components, only the 1D system was obtained. However, these complexes were found to exhibit properties as a 1D system. Furthermore, it was observed that the electronic properties at low temperature were severely affected by the defects or impurities in the crystal due to their highly one-dimensional electronic structure. These results provide evidence that most of the M(Pc)Xy one-dimensional partially oxidized salts do not show metal-to-insulator transitions with definite lattice distortions down to very low temperature.

引用

页码：5503 / 5533

页数：31

共 133 条

[1] UNUSUAL BAND-FILLING AND COUNTERION ORDERING EFFECTS IN A PHTHALOCYANINE MOLECULAR-METAL - SINGLE-CRYSTAL STUDIES OF NI(PC)(CLO4)Y [J].

ALMEIDA, M ;

KANATZIDIS, MG ;

TONGE, LM ;

MARKS, TJ ;

MARCY, HO ;

MCCARTHY, WJ ;

KANNEWURF, CR .

SOLID STATE COMMUNICATIONS, 1987, 63 (06) :457-461

[2] ELECTRICAL AND MAGNETIC-PROPERTIES OF THIN-FILMS AND SINGLE-CRYSTALS OF BIS(PHTHALOCYANINATO)LUTETIUM [J].

ANDRE, JJ ;

HOLCZER, K ;

PETIT, P ;

RIOU, MT ;

CLARISSE, C ;

EVEN, R ;

FOURMIGUE, M ;

SIMON, J .

CHEMICAL PHYSICS LETTERS, 1985, 115 (4-5) :463-466

[3] Novel phthalocyanine conductor containing two-dimensional Pc stacks, [PXX]2[Co(Pc)(CN)2] (PXX=peri-xanthenoxanthene, Co(Pc)(CN)2=dicyano(phthalocyaninato)cobalt(III)) [J].

Asari, T ;

Naito, T ;

Inabe, T ;

Matsuda, M ;

Tajima, H .

CHEMISTRY LETTERS, 2004, 33 (02) :128-129

[4] Charge-transfer complexes of PXX (PXX=6,12-dioxaanthanthrene). The formal charge and molecular geometry [J].

Asari, T ;

Kobayashi, N ;

Naito, T ;

Inabe, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (01) :53-58

[5]

Bernier P., 1999, Advances in Synthetic Metals: Twenty Years of Progress in Science and Technology

[6] EPR study of the x, α and β structures of lithium phthalocyanine [J].

Brinkmann, M ;

Turek, P ;

Andre, JJ .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (03) :675-685

[7] INTERLIGAND C-C SIGMA-BOND BREAKING AND REPAIR IN A STAPLED BIS(PHTHALOCYANINATO)TITANIUM COMPLEX - SYNTHESIS, CHARACTERIZATION, AND ELECTRICAL-CONDUCTIVITY PROPERTIES OF OXIDATION-PRODUCTS OF BIS(PHTHALOCYANINATO)TITANIUM(IV) AND BIS(PHTHALOCYANINATO)TIN(IV) AND X-RAY CRYSTAL-STRUCTURE OF [PC2TI](I3)0.66 [J].

CAPOBIANCHI, A ;

ERCOLANI, C ;

PAOLETTI, AM ;

PENNESI, G ;

ROSSI, G ;

CHIESIVILLA, A ;

RIZZOLI, C .

INORGANIC CHEMISTRY, 1993, 32 (21) :4605-4611

[8] THERMOPOWER IN CORRELATED HOPPING REGIME [J].

CHAIKIN, PM ;

BENI, G .

PHYSICAL REVIEW B, 1976, 13 (02) :647-651

[9] Concerted supramolecular moths: Linear columns and zigzag chains of multiple phenyl embraces involving Ph(4)P(+) cations in crystals [J].

Dance, I ;

Scudder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (19) :3755-3769

[10]

DAROUSKIKH AN, 1986, KRISTALLOGRAFIYA, V31, P455

← 1 2 3 4 5 6 7 8 9 10 →