On the use of seven-membered phosphorous heterocycles based on 2,2′-dihydroxy-1,1′-binaphthalene and 1,4:3,6-dianhydro-D-mannitol in the 31P NMR analysis of the enantiomeric composition of chiral alcohols

被引：10

作者：

Bredikhin, AA ^{[1
]}

Bredikhina, ZA ^{[1
]}

Nigmatzyanov, FF ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 03期

关键词：

2,2 '-dihydroxy-1,1 '-binaphthalene (BINOL); 1,4 : 3,6-dianhydro-D-mannitol; phosphorylation; chiral alcohols; chiral derivatizing agents; enantiomeric composition; P-31; NMR;

D O I：

10.1007/BF02495644

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Some aspects of phosphorylation of 2,2'-dihydroxy-1,1'-binaphthalene (BINOL) and 1,4:3,6-dianhydro-D-mannitol (isomannide) were investigated. The possibility of using the corresponding cyclic chloro-and amidophosphites for the analysis of enantiomeric compositions of chiral primary and secondary alcohols by P-31 NMR was examined.

引用

页码：411 / 416

页数：6

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