Three-dimensional imaging of colloidal glasses under steady shear

被引:214
作者
Besseling, R.
Weeks, Eric R.
Schofield, A. B.
Poon, W. C. K.
机构
[1] Univ Edinburgh, Scottish Univ Phys Alliance, Edinburgh EH9 3JZ, Midlothian, Scotland
[2] Univ Edinburgh, Sch Phys, Edinburgh EH9 3JZ, Midlothian, Scotland
[3] Emory Univ, Dept Phys, Atlanta, GA 30322 USA
基金
英国工程与自然科学研究理事会;
关键词
HIGHLY SUPERCOOLED LIQUIDS; HARD-SPHERE SUSPENSIONS; SELF-DIFFUSION; DIRECT VISUALIZATION; INDUCED ORDER; FLOW; DYNAMICS; MICROSCOPY; SOFT; HETEROGENEITIES;
D O I
10.1103/PhysRevLett.99.028301
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Using fast confocal microscopy we image the three-dimensional dynamics of particles in a yielded hard-sphere colloidal glass under steady shear. The structural relaxation, observed in regions with uniform shear, is nearly isotropic but is distinctly different from that of quiescent metastable colloidal fluids. The inverse relaxation time tau(-1)(alpha) and diffusion constant D, as functions of the local shear rate (gamma) over dot, show marked shear thinning with tau(-1)(alpha)proportional to D proportional to (gamma) over dot(0.8) over more than two decades in (gamma) over dot. In contrast, the global rheology of the system displays Herschel-Bulkley behavior. We discuss the possible role of large scale shear localization and other mechanisms in generating this difference.
引用
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页数:4
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