Palladium-iminophosphine-catalyzed homocoupling of alkynylstannanes and other organostannanes using allyl acetate or air as an oxidant

被引：43

作者：

Shirakawa, E

Nakao, Y

Murota, Y

Hiyama, T

机构：

[1] Japan Adv Inst Sci & Technol, Grad Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 670卷 / 1-2期

关键词：

oxidative homocoupling; organostannane; palladium; iminophosphine;

D O I：

10.1016/S0022-328X(02)02153-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A palladium-iminophosphine complex was found to catalyze the homocoupling reaction of alkynylstannanes using allyl acetate as an oxidant, whereas aryl- and alkenylstannanes were oxidatively homocoupled with air. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：132 / 136

页数：5

共 34 条

[1] REACTIONS OF RU3 CLUSTERS WITH FUNCTIONAL PHOSPHINES - FORMATION OF MU-3-ACYL AND MU-3-IMIDOYL COMPLEXES [J].