Experimental study on adsorption kinetics of activated carbon/R134a and activated carbon/R507A pairs

被引:45
作者
Habib, Khairul [2 ]
Saha, Bidyut B. [1 ]
Rahman, Kazi A. [3 ]
Chakraborty, Anutosh [3 ]
Koyama, Shigeru [2 ]
Ng, Kim Choon [3 ]
机构
[1] Kyushu Univ, Dept Mech Engn, Fukuoka 8190395, Japan
[2] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Kasuga, Fukuoka 8168580, Japan
[3] Natl Univ Singapore, Dept Mech Engn, Singapore 119260, Singapore
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 2010年 / 33卷 / 04期
关键词
Adsorption system; Activated carbon; R134a; R507A; Experiment; Adsorption; BED ADSORPTION; PURIFICATION; MEMBRANE; CHILLER; DESIGN; SYSTEM; DRIVEN;
D O I
10.1016/j.ijrefrig.2010.01.006
中图分类号
O414.1 [热力学];
学科分类号
摘要
The objective of this article is to evaluate adsorption kinetics of R134a and R507A on pitch based activated carbon experimentally by a constant volume variable pressure method at different adsorption temperatures ranging from 20 to 60 degrees C. These data are useful for the design of adsorption cooling and refrigeration systems and are unavailable in the literature. Data obtained from the kinetic studies were analyzed with various kinetic models and the Fickian diffusion model is found to be the most suitable overall. Guided by the experimental measurements, the surface diffusion is also estimated and is found that it follows the classical Arrhenius law within the experimental range. (C) 2010 Elsevier Ltd and IIR. All rights reserved.
引用
收藏
页码:706 / 713
页数:8
相关论文
共 22 条
[11]   Dynamics of natural gas adsorption storage systems employing activated carbon [J].
Mota, JPB ;
Rodrigues, AE ;
Saatdjian, E ;
Tondeur, D .
CARBON, 1997, 35 (09) :1259-1270
[12]  
Ruthven D. M, 1984, Principle of Adsorption and Adsorption Processes Chap. 23
[13]   Performance evaluation of a low-temperature waste heat driven multi-bed adsorption chiller [J].
Saha, BB ;
Koyama, S ;
Lee, JB ;
Kuwahara, K ;
Alam, KCA ;
Hamamoto, Y ;
Akisawa, A ;
Kashiwagi, T .
INTERNATIONAL JOURNAL OF MULTIPHASE FLOW, 2003, 29 (08) :1249-1263
[14]   Adsorption of equal mass fraction near an azeotropic mixture of pentafluoroethane and 1,1,1-trifluoroethane on activated carbon [J].
Saha, Bidyut B. ;
El-Sharkawy, Ibrahim I. ;
Habib, Khairul ;
Koyama, Shigeru ;
Srinivasan, Kandadai .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (08) :1872-1876
[15]   Evaluation of adsorption parameters and heats of adsorption through desorption measurements [J].
Saha, Bidyut B. ;
Koyama, Shigeru ;
El-Sharkawy, Ibrahim I. ;
Habib, Khairul ;
Srinivasan, Kandadai ;
Dutta, Pradip .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (06) :2419-2424
[16]   Adsorption characteristics and heat of adsorption measurements of R-134a on activated carbon [J].
Saha, Bidyut B. ;
Habib, Khairul ;
El-Sharkawy, Ibrahim I. ;
Koyama, Shigeru .
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2009, 32 (07) :1563-1569
[17]   Isotherms and thermodynamics for the adsorption of n-butane on pitch based activated carbon [J].
Saha, Bidyut Baran ;
Chakraborty, Anutosh ;
Koyama, Shigeru ;
Yoon, Seong-Ho ;
Mochida, Isao ;
Kumja, M. ;
Yap, Christopher ;
Ng, Kim Choon .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2008, 51 (7-8) :1582-1589
[18]   A new generation cooling device employing CaCl2-in-silica gel-water system [J].
Saha, Bidyut Baran ;
Chakraborty, Anutosh ;
Koyama, Shigeru ;
Aristov, Yu I. .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2009, 52 (1-2) :516-524
[19]   AN INTERNATIONAL STANDARD FORMULATION FOR THE THERMODYNAMIC PROPERTIES OF 1,1,1,2-TETRAFLUROETHANE (HFC-134A) FOR TEMPERATURES FROM 170-K TO 455-K AND PRESSURES UP TO 70-MPA [J].
TILLNERROTH, R ;
BAEHR, HD .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1994, 23 (05) :657-729
[20]   Experimental study of adsorption chiller driven by variable heat source [J].
Wang, D. C. ;
Wang, Y. J. ;
Zhang, J. P. ;
Tian, X. L. ;
Wu, J. Y. .
ENERGY CONVERSION AND MANAGEMENT, 2008, 49 (05) :1063-1073