Methyltrioxorhenium catalyzed aerobic oxidation of organonitrogen compounds

被引:30
作者
Sharma, VB [1 ]
Jain, SL [1 ]
Sain, B [1 ]
机构
[1] Indian Inst Petr, Chem & Biosci Div, Dehra Dun 248005, Uttar Pradesh, India
关键词
methyltrioxorhenium; molecular oxygen; oxidation; organonitrogen compounds;
D O I
10.1016/S0040-4039(03)00639-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of tertiary, secondary and primary organonitrogen compounds have been efficiently and selectivity oxidized to their corresponding N-oxides, nitrones, and nitro compounds with molecular oxygen using methyltrioxorhenium as catalyst. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3235 / 3237
页数:3
相关论文
共 29 条
[1]   Sharpless asymmetric dihydroxylation on an industrial scale [J].
Ahrgren, L ;
Sutin, L .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1997, 1 (06) :425-427
[2]   Additions of organometallic reagents to C=N bonds: Reactivity and selectivity [J].
Bloch, R .
CHEMICAL REVIEWS, 1998, 98 (04) :1407-1438
[3]  
Cope A. C., 1963, ORG SYNTH, VIV, P612
[4]  
Cope A. C., 1960, ORG REACTIONS, V11, P317
[5]  
COPE AC, 1993, ULLMANNS ENCY IND A, V22, P399
[6]   ALKANE OXIDATIONS BY A NOVEL MU-3-OXO TRINUCLEAR RUTHENIUM CARBOXYLATE COMPLEX [J].
DAVIS, S ;
DRAGO, RS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (03) :250-251
[7]   Osmium-catalyzed dihydroxylation of olefins using dioxygen or air as the terminal oxidant [J].
Döbler, C ;
Mehltretter, GM ;
Sundermeier, U ;
Beller, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (42) :10289-10297
[8]   Atom-transfer reactions catalyzed by methyltrioxorhenium(VII) - mechanisms and applications [J].
Espenson, JH .
CHEMICAL COMMUNICATIONS, 1999, (06) :479-488
[9]   Asymmetric 1,3-dipolar cycloaddition reactions [J].
Gothelf, KV ;
Jorgensen, KA .
CHEMICAL REVIEWS, 1998, 98 (02) :863-909
[10]   Organorhenium oxides [J].
Herrmann, WA ;
Kuhn, FE .
ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (04) :169-180