Disinfection performance of Fe(VI) in water and wastewater: a review

被引:133
作者
Sharma, V. K. [1 ]
机构
[1] Florida Inst Technol, Melbourne, FL 32901 USA
关键词
disinfectant; disinfection; Fe(VI); treatment; wastewater; water; HETEROGENEOUS PHOTOCATALYTIC REDUCTION; IRRADIATED TITANIA SUSPENSIONS; POTASSIUM FERRATE(VI); OXIDATION; INACTIVATION; COAGULATION; REMOVAL; OXIDANT; POLLUTANTS; MECHANISM;
D O I
10.2166/wst.2007.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Ferrate(VI) [(FeO42-)-O-VI, Fe(VI)] has excellent disinfectant properties and can inactivate a wide variety of microorganisms at low Fe(VI) dosages. The final product of Fe(VI) is Fe(III), a non-toxic Compound. The treatment by Fe(VI) does not give any chlorination by-products, which makes Fe(VI) an environmentally-friendly ion. The results demonstrate that Fe(VI) can inactivate Escherichia coli (E. coli) at lower dosages or shorter contact time than hypochlorite. Fe(VI) can also kill many chlorine resistant organisms, such as aerobic spore-formers and sulphite-reducing clostridia, and would be highly effective in treating emerging toxins in the aquatic environment. Fe(VI) can thus be used as an effective alternate disinfectant for the treatment of water and wastewater. Moreover, Fe(VI) is now becoming economically available in commercial quantities and can be used as a treatment chemical to meet the water demand of this century. This paper reviews the potential role of Fe(VI) as disinfectant in water and wastewater treatment processes.
引用
收藏
页码:225 / 232
页数:8
相关论文
共 39 条
[31]   Heterogeneous photocatalytic reduction of ferrate(VI) in UV-irradiated titania suspensions: Role in enhancing destruction of nitrogen-containing pollutants [J].
Sharma, VK ;
Winkelmann, K ;
Krasnova, Y ;
Lee, C ;
Sohn, M .
INTERNATIONAL JOURNAL OF PHOTOENERGY, 2003, 5 (03) :183-190
[32]   Ferrate(V) oxidation of pollutants: a premix pulse radiolysis study [J].
Sharma, VK .
RADIATION PHYSICS AND CHEMISTRY, 2002, 65 (4-5) :349-355
[33]   Dissociation constants of the monoprotic ferrate(VI) ion in NaCl media [J].
Sharma, VK ;
Burnett, CR ;
Millero, FJ .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (11) :2059-2062
[34]   Heterogeneous photocatalytic reduction of ferrate(VI) in UV-irradiated titania suspensions [J].
Sharma, VK ;
Burnett, CR ;
Rivera, W ;
Joshi, VN .
LANGMUIR, 2001, 17 (15) :4598-4601
[35]  
SHARMA VK, 2006, IN PRESS ENV CHEM LE
[36]   PREPARATION AND PURIFICATION OF POTASSIUM FERRATE .6. [J].
THOMPSON, GW ;
OCKERMAN, LT ;
SCHREYER, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (03) :1379-1381
[37]  
WAITE TD, 1979, ASCEJ ENV ENG DIV, V105, P1023
[38]  
WATSON HE, 2008, J HYG, V8, P356
[39]   Removal of cyanobacterial microcystin-LR by ferrate oxidation-coagulation [J].
Yuan, BL ;
Qu, JH ;
Fu, ML .
TOXICON, 2002, 40 (08) :1129-1134