Biosynthesis of 2-C-methyl-D-erythritol in plants by rearrangement of the terpenoid precursor, 1-deoxy-D-xylulose 5-phosphate

被引：38

作者：

Sagner, S

Eisenreich, W

Fellermeier, M

Latzel, C

Bacher, A

Zenk, MH

机构：

[1] Univ Munich, Lehrstuhl Pharmazeut Biol, D-80333 Munich, Germany

[2] Tech Univ Munich, Inst Organ Chem & Biochem, D-85747 Garching, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(98)00296-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Leaves of Liriodendron tulipifera convert 1-deoxy-D-xylulose to 2-C-methyl-D-erythritol via a skeletal rearrangement reminiscent of the formation of terpene precursors from l-deoxy-D-xylulose. The data suggest that 2-C-methyl-D-erythritol 4-phosphate is either an intermediate or a side product of the deoxyxylulose 4-phosphate pathway of terpenoid biosynthesis. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：2091 / 2094

页数：4

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