Dynamic hemicarcerands and hemicarceplexes

被引：100

作者：

Ro, S ^{[1
]}

Rowan, SJ ^{[1
]}

Pease, AR ^{[1
]}

Cram, DJ ^{[1
]}

Stoddart, JF ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 16期

关键词：

D O I：

10.1021/ol005962p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The reversible nature of the imine bond formation in CDCl3 solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C(2)B(4)circle dot Fc dissolved in CDCl3 to give the hemicarcerand C2B4 when excess of both MPD and trifluoroacetic acid are present.

引用

页码：2411 / 2414

页数：4

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