Recent advances on supramolecular isomerism in metal organic frameworks

被引:71
作者
Karmakar, Anirban [1 ]
Paul, Anup [1 ]
Pombeiro, Armando J. L. [1 ]
机构
[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1049001 Lisbon, Portugal
来源
CRYSTENGCOMM | 2017年 / 19卷 / 32期
关键词
SINGLE-CRYSTAL TRANSFORMATION; SECONDARY BUILDING UNITS; DIFFERENT HELICAL UNITS; COORDINATION POLYMERS; TOPOLOGICAL ISOMERISM; HENRY REACTION; STRUCTURAL TRANSFORMATIONS; CONFORMATIONAL ISOMERISM; SPONTANEOUS RESOLUTION; MAGNETIC-PROPERTIES;
D O I
10.1039/c7ce00756f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-organic frameworks (MOFs) or coordination polymers (CPs), a class of compounds constructed often by self-assembly of inorganic metal ions and organic ligands, have attracted growing interest on account of their diverse structures, permanent porosity and tunable properties, with a prospect for various applications. In some cases, the self-assembly of the building blocks produces different MOFs with the same molecular composition, i.e., supramolecular isomers. The design of supramolecular isomers in the area of MOFs is challenging and this highlight gathers recently published articles concerning the different types of supramolecular isomers, i.e., structural, conformational, catenane and optical, in this area. The syntheses and structures of the isomers and their comparison are presented, as well as the role of various parameters, such as temperature, solvent, concentration, crystallization method, additive and template, in the formation of the different supramolecular isomers, by analyzing selected examples.
引用
收藏
页码:4666 / 4695
页数:30
相关论文
共 107 条
[81]   Supramolecular Isomerism and Polyrotaxane-Based Two-Dimensional Coordination Polymers [J].
Park, In-Hyeok ;
Ju, Huiyeong ;
Herng, Tun Seng ;
Kang, Yunji ;
Lee, Shim Sung ;
Ding, Jun ;
Vittal, Jagadese J. .
CRYSTAL GROWTH & DESIGN, 2016, 16 (12) :7278-7285
[82]   Guest-Triggered Supramolecular Isomerism in a Pillared-Layer Structure with Unusual Isomers of Paddle-Wheel Secondary Building Units by Reversible Single-Crystal-to-Single-Crystal Transformation [J].
Park, In-Hyeok ;
Lee, Shim Sung ;
Vittal, Jagadese J. .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (08) :2695-2702
[83]   Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal Treatment in a Metal-Organic Framework [J].
Park, Jinhee ;
Yuan, Daqiang ;
Pham, Khanh T. ;
Li, Jian-Rong ;
Yakovenko, Andrey ;
Zhou, Hong-Cai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :99-102
[84]   Amide functionalized metal-organic frameworks for diastereoselective nitroaldol (Henry) reaction in aqueous medium [J].
Paul, Anup ;
Karmakar, Anirban ;
Guedes da Silva, M. Fatima C. ;
Pombeiro, Armando J. L. .
RSC ADVANCES, 2015, 5 (106) :87400-87410
[85]   Metal-organic framework membranes: from synthesis to separation application [J].
Qiu, Shilun ;
Xue, Ming ;
Zhu, Guangshan .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :6116-6140
[86]   Very large breathing effect in the first nanoporous chromium(III)-based solids:: MIL-53 or CrIII(OH)•{O2C-C6H4-CO2}•{HO2C-C6H4-CO2H}x•H2Oy [J].
Serre, C ;
Millange, F ;
Thouvenot, C ;
Noguès, M ;
Marsolier, G ;
Louër, D ;
Férey, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13519-13526
[87]   Three topological isomeric coordination polymer networks from the assembly of a rigid linear spacer and a square planar metal node: Structures, isomerism control, and solid-to-solid transformation [J].
Shin, DM ;
Lee, IS ;
Cho, D ;
Chung, YK .
INORGANIC CHEMISTRY, 2003, 42 (24) :7722-7724
[88]   Light-triggered Supramolecular Isomerism in a Self-catenated Zn(II)-organic Framework: Dynamic Photo-switching CO2 Uptake and Detection of Nitroaromatics [J].
Song, Wei-Chao ;
Cui, Xun-Zhe ;
Liu, Zhong-Yi ;
Yang, En-Cui ;
Zhao, Xiao-Jun .
SCIENTIFIC REPORTS, 2016, 6
[89]   Temperature-dependent supramolecular stereoisomerism in porous copper coordination networks based on a designed carboxylate ligand [J].
Sun, DF ;
Ke, YX ;
Mattox, TM ;
Ooro, BA ;
Zhou, HC .
CHEMICAL COMMUNICATIONS, 2005, (43) :5447-5449
[90]   Chiral magnetic metal-organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution [J].
Tong, Xiao-Lan ;
Hu, Tong-Liang ;
Zhao, Jiong-Peng ;
Wang, Yue-Kui ;
Zhang, Hui ;
Bu, Xian-He .
CHEMICAL COMMUNICATIONS, 2010, 46 (45) :8543-8545