Fluctuation theorem and Onsager reciprocity relations

被引：160

作者：

Andrieux, D ^{[1
]}

Gaspard, P ^{[1
]}

机构：

[1] Free Univ Brussels, Ctr Nonlinear Phenomena & Complex Syst, B-1050 Brussels, Belgium

来源：

JOURNAL OF CHEMICAL PHYSICS | 2004年 / 121卷 / 13期

关键词：

D O I：

10.1063/1.1782391

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Onsager and higher-order reciprocity relations are derived from a fluctuation theorem for nonequilibrium reactions ruled by the chemical master equation. The fluctuation theorem is obtained for the generating function of the macroscopic fluxes between chemiostats maintaining the system in a nonequilibrium steady state. The macroscopic affinities associated with the fluxes are identified by graph theory. The Yamamoto-Zwanzig formulas for the reaction constants are also derived from the fluctuation theorem. (C) 2004 American Institute of Physics.

引用

页码：6167 / 6174

页数：8

共 22 条

[1]

ANDRIEUX D, UNPUB

[2]

Callen HB., 1985, THERMODYNAMICS INTRO, V2, DOI 10.1119/1.19071

[3] PROBABILITY OF 2ND LAW VIOLATIONS IN SHEARING STEADY-STATES [J].

EVANS, DJ ;

COHEN, EGD ;

MORRISS, GP .

PHYSICAL REVIEW LETTERS, 1993, 71 (15) :2401-2404

[4] EQUILIBRIUM MICROSTATES WHICH GENERATE 2ND LAW VIOLATING STEADY-STATES [J].

EVANS, DJ ;

SEARLES, DJ .

PHYSICAL REVIEW E, 1994, 50 (02) :1645-1648

[5] DYNAMICAL ENSEMBLES IN NONEQUILIBRIUM STATISTICAL-MECHANICS [J].

GALLAVOTTI, G ;

COHEN, EGD .

PHYSICAL REVIEW LETTERS, 1995, 74 (14) :2694-2697

[6] Extension of Onsager's reciprocity to large fields and the chaotic hypothesis [J].

Gallavotti, G .

PHYSICAL REVIEW LETTERS, 1996, 77 (21) :4334-4337

[7] Fluctuation theorem for nonequilibrium reactions [J].

Gaspard, P .

JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (19) :8898-8905

[8]

HILL TL, 1966, J THEOR BIOL, V36, P133

[9]

Kondepudi D., 1998, MODERN THERMODYNAMIC

[10] Fluctuation theorem for stochastic dynamics [J].

Kurchan, J .

JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1998, 31 (16) :3719-3729

← 1 2 3 →