Templating open- and closed-chain structures around metal complexes of macrocycles

被引：32

作者：

Heath, SL

Laye, RH

Muryn, CA

Lima, N

Sessoli, R

Shaw, R

Teat, SJ

Timco, GA

Winpenny, RER

机构：

[1] INSTM, I-50019 Sesto Fiorentino, Italy

[2] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[4] Univ Studi Firenze, Lab Magnetismo Mol, Dipartimento Chim, I-50019 Sesto Fiorentino, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

chromium; heterometallic complexes; nickel; supramolecular chemistry; template synthesis;

D O I：

10.1002/anie.200461006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ringing the changes: Complexes of azamacrocycles were used for the template synthesis of extraordinary new cyclic and acyclic chromium-nickel chains, which include the S"-shaped cluster shown (see picture) obtained when a cyclen-based template is used. The results suggest a new method for making sophisticated polymetallic architectures."

引用

页码：6132 / 6135

页数：4

共 26 条

[1] The magnetic Mobius strip: Synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels [J].

Cador, O ;

Gatteschi, D ;

Sessoli, R ;

Larsen, FK ;

Overgaard, J ;

Barra, AL ;

Teat, SJ ;

Timco, GA ;

Winpenny, REP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (39) :5196-5200

[2]

Cador O., 2004, ANGEW CHEM, V116, P5308

[3]

CHABOUSSANT G, 2004, J CHEM SOC DA, P2757

[4]

CORNIA A, 2004, COMPREHENSIVE COORDI, V7, P779

[5] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[6] PHASE-TRANSITION IN THE 2D XY MODEL [J].

GUPTA, R ;

DELAPP, J ;

BATROUNI, GG ;

FOX, GC ;

BAILLIE, CF ;

APOSTOLAKIS, J .

PHYSICAL REVIEW LETTERS, 1988, 61 (17) :1996-1999

[7] Metal string complexes:: Synthesis and crystal structure of [Ni4(μ4-phdpda)4] and [Ni7(μ7-(teptra)4Cl2] (H2phdpda = N-phenyldipyridyldiamine and H3teptra = tetrapyridyltriamine) [J].

Lai, SY ;

Lin, TW ;

Chen, YH ;

Wang, CC ;

Lee, GH ;

Yang, MH ;

Leung, MK ;

Peng, SM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) :250-251

[8]

Larsen F.K., 2003, Angew. Chem, V115, P105, DOI DOI 10.1002/ANGE.200390002

[9] Horseshoes, rings, and distorted rings: Studies of cyclic chromium-fluoride cages [J].

Larsen, FK ;

Overgaard, J ;

Parsons, S ;

Rentschler, E ;

Smith, AA ;

Timco, GA ;

Winpenny, REP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (48) :5978-5981

[10] Synthesis and chracterization of heterometallic [Cr7M] wheels [J].

Larsen, FK ;

McInnes, EJL ;

El Mkami, H ;

Overgaard, J ;

Piligkos, S ;

Rajaraman, G ;

Rentschler, E ;

Smith, AA ;

Smith, GM ;

Boote, V ;

Jennings, M ;

Timco, GA ;

Winpenny, REP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :101-105

← 1 2 3 →