A novel two-dimensional rectangular network.: Synthesis and structure of {[Cu(4,4′-bpy)(pyz)(H2O)2][PF6]2}n (4,4′-bpy equals 4,4′-bipyridine, pyz equals pyrazine)

被引:166
作者
Tong, ML
Chen, XM [1 ]
Yu, XL
Mak, TCW
机构
[1] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Hong Kong
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 01期
关键词
D O I
10.1039/a706363f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex {[Cu(4,4'-bpy)(pyz)(H2O)(2)][PF6](2)}. comprising two-dimensional rectangular grids with each cavity enclosed by two 4,4'-bipyridine (4,4'-bipy) and two pyrazine (pyz) ligands, which superpose in an off-set fashion to give smaller rectangular channels, has been prepared and characterized by single-crystal X-ray structural analysis.
引用
收藏
页码:5 / 6
页数:2
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