Addition of non-reacting gases to the anode flow field of DMFCs leading to improved performance

被引:38
作者
Yang, H [1 ]
Zhao, TS [1 ]
Ye, Q [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Mech Engn, Kowloon, Hong Kong, Peoples R China
关键词
direct methanol fuel cells; two-phase flow; gas injection; flow velocity; void fraction; flow field;
D O I
10.1016/j.elecom.2004.08.012
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Contrary to conventional conceptions, we find that an external addition of non-reacting gases to the anode flow field of a direct methanol fuel cell led to improved cell performance. Our theoretical analysis shows that an increase in void fraction of the gas phase in flow channels reduces the cross sectional area of the liquid phase, thereby increasing the liquid velocity. The increased liquid velocity enhances the mass transfer of methanol from the flow channel to the gas diffusion layer and hence, improves cell performance. Following the same idea of accelerating the liquid velocity by reducing channel depth, we further demonstrate experimentally that thinning channel from 3.0 to 0.5 mm resulted in an increase in peak power density by 67.5%. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1098 / 1103
页数:6
相关论文
共 35 条
[21]   Open circuit voltage and methanol crossover in DMFCs [J].
Qi, ZG ;
Kaufman, A .
JOURNAL OF POWER SOURCES, 2002, 110 (01) :177-185
[22]   Methanol transport through nafion membranes - Electro-osmotic drag effects on potential step measurements [J].
Ren, XM ;
Springer, TE ;
Zawodzinski, TA ;
Gottesfeld, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (02) :466-474
[23]   High performance direct methanol polymer electrolyte fuel cells [J].
Ren, XM ;
Wilson, MS ;
Gottesfeld, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :L12-L15
[24]   Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality [J].
Roy, SC ;
Christensen, PA ;
Hamnett, A ;
Thomas, KM ;
Trapp, V .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (10) :3073-3079
[25]   Predictors of quality of life in rural patients with cancer [J].
Schultz, AA ;
Winstead-Fry, P .
CANCER NURSING, 2001, 24 (01) :12-19
[26]   Electrochemical and gas evolution characteristics of direct methanol fuel cells with stainless steel mesh flow beds [J].
Scott, K ;
Argyropoulos, P ;
Yiannopoulos, P ;
Taama, WM .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (08) :823-832
[27]   Material aspects of the liquid feed direct methanol fuel cell [J].
Scott, K ;
Taama, WM ;
Argyropoulos, P .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1998, 28 (12) :1389-1397
[28]   A solid-polymer electrolyte direct methanol fuel cell with a mixed reactant and air anode [J].
Shukla, AK ;
Jackson, CL ;
Scott, K ;
Murgia, G .
JOURNAL OF POWER SOURCES, 2002, 111 (01) :43-51
[29]   Direct methanol fuel cells: progress in cell performance and cathode research [J].
Thomas, SC ;
Ren, XM ;
Gottesfeld, S ;
Zelenay, P .
ELECTROCHIMICA ACTA, 2002, 47 (22-23) :3741-3748
[30]   Nonelectrochemical pathway of methanol oxidation at a platinum-catalyzed oxygen gas diffusion electrode [J].
Vielstich, W ;
Paganin, VA ;
Lima, FHB ;
Ticianelli, EA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (05) :A502-A505