Synthetic and kinetic aspects of nickel-catalysed amination of allylic alcohol derivatives

被引：40

作者：

Bricout, H ^{[1
]}

Carpentier, JF ^{[1
]}

Mortreux, A ^{[1
]}

机构：

[1] Ecole Natl Super Chim Lille, Grp Chim Organ Appl, CNRS, Catalyse Heterogene & Homogene Lab, F-59652 Villeneuve Dascq, France

来源：

TETRAHEDRON | 1998年 / 54卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(97)10208-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The design of efficient nickel-based catalytic systems for coupling of diethylamine (1) with esters and ether derivatives of allyl alcohol (2a-c) and related allyl-substituted compounds (4a-e) is reported. Special attention is paid to solvent and salt effects on catalytic activities and kinetic profiles for the formation of allylamines. The results are discussed in terms of the influence of some reaction parameters (polarity, ion exchange processes, substrate) on the rate determining step of the catalytic cycle. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1073 / 1084

页数：12

共 31 条

[1]

AKERMARK B, 1985, ORGANOMETALLICS, V4, P1275

[2] NICKEL-CATALYZED ALLYLATION OF STABLE ENOLATES BY ALLYLIC ETHERS AND ALLYLIC ALCOHOLS [J].