Structural assignment of tetrabromostyloguanidine:: Does the relative configuration of the palau'amines need revision?

被引：89

作者：

Grube, Achim ^{[1
]}

Koeck, Matthias ^{[1
]}

机构：

[1] Alfred Wegener Inst Polar & Marine Res, Helmholtz Gemeinschaft, D-27570 Bremerhaven, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 13期

关键词：

configuration determination; natural products; NMR spectroscopy; Palau'amines; structure elucidation;

D O I：

10.1002/anie.200604076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Products of the Caribbean: The palau'amine derivative tetrabromostyloguanidine 1 was isolated from the sponge Stylissa caribica and the elucidation of its structure with the focus on the relative configuration is discussed in detail. Results from NMR studies and molecular calculations suggest that the relative configuration for members of the palau'amine family differs from that earlier reported. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2320 / 2324

页数：5

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