Single step, complementary doping of graphene

被引:77
作者
Brenner, Kevin [1 ]
Murali, Raghunath [1 ]
机构
[1] Georgia Inst Technol, Nanotechnol Res Ctr, Atlanta, GA 30332 USA
关键词
bonds (chemical); elemental semiconductors; graphene; polymer films; semiconductor doping; semiconductor junctions; semiconductor thin films; FILMS; GAS;
D O I
10.1063/1.3308482
中图分类号
O59 [应用物理学];
学科分类号
摘要
A single-step doping method capable of high resolution n- and p-type doping of large area graphene is presented. Thin films of hydrogen silsesquoxane on exfoliated graphene are used to demonstrate both electron and hole doping through control of the polymer cross-linking process. This dual-doping is attributed to the mismatch in bond strength of the Si-H and Si-O bonds in the film as well as out-gassing of hydrogen with increasing cross-linking. A high-resolution graphene p-n junction is demonstrated using this method.
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页数:3
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共 15 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Doping Single-Layer Graphene with Aromatic Molecules [J].
Dong, Xiaochen ;
Fu, Dongliang ;
Fang, Wenjing ;
Shi, Yumeng ;
Chen, Peng ;
Li, Lain-Jong .
SMALL, 2009, 5 (12) :1422-1426
[3]   Behavior of a chemically doped graphene junction [J].
Farmer, Damon B. ;
Lin, Yu-Ming ;
Afzali-Ardakani, Ali ;
Avouris, Phaedon .
APPLIED PHYSICS LETTERS, 2009, 94 (21)
[4]   Chemical Doping and Electron-Hole Conduction Asymmetry in Graphene Devices [J].
Farmer, Damon B. ;
Golizadeh-Mojarad, Roksana ;
Perebeinos, Vasili ;
Lin, Yu-Ming ;
Tulevski, George S. ;
Tsang, James C. ;
Avouris, Phaedon .
NANO LETTERS, 2009, 9 (01) :388-392
[5]   Evidence of the role of contacts on the observed electron-hole asymmetry in graphene [J].
Huard, B. ;
Stander, N. ;
Sulpizio, J. A. ;
Goldhaber-Gordon, D. .
PHYSICAL REVIEW B, 2008, 78 (12)
[6]   Oxygen-induced p-type doping of a long individual single-walled carbon nanotube [J].
Kang, D ;
Park, N ;
Ko, JH ;
Bae, E ;
Park, W .
NANOTECHNOLOGY, 2005, 16 (08) :1048-1052
[7]   Graphene oxidation: Thickness-dependent etching and strong chemical doping [J].
Liu, Li ;
Ryu, Sunmin ;
Tomasik, Michelle R. ;
Stolyarova, Elena ;
Jung, Naeyoung ;
Hybertsen, Mark S. ;
Steigerwald, Michael L. ;
Brus, Louis E. ;
Flynn, George W. .
NANO LETTERS, 2008, 8 (07) :1965-1970
[8]   Two-dimensional gas of massless Dirac fermions in graphene [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Katsnelson, MI ;
Grigorieva, IV ;
Dubonos, SV ;
Firsov, AA .
NATURE, 2005, 438 (7065) :197-200
[9]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669
[10]   n-Type Behavior of Graphene Supported on Si/SiO2 Substrates [J].
Romero, Hugo E. ;
Shen, Ning ;
Joshi, Prasoon ;
Gutierrez, Humberto R. ;
Tadigadapa, Srinivas A. ;
Sofo, Jorge O. ;
Eklund, Peter C. .
ACS NANO, 2008, 2 (10) :2037-2044