Metal-Organic Polyhedral Frameworks: High H2 Adsorption Capacities and Neutron Powder Diffraction Studies

被引：255

作者：

Yan, Yong ^{[1
]}

Telepeni, Irvin ^{[2
]}

Yang, Sihai ^{[1
]}

Lin, Xiang ^{[1
]}

Kockelmann, Winfried ^{[3
]}

Dailly, Anne ^{[4
]}

Blake, Alexander J. ^{[1
]}

Lewis, William ^{[1
]}

Walker, Gavin S. ^{[2
]}

Allan, David R. ^{[5
]}

Barnett, Sarah A. ^{[5
]}

Champness, Neil R. ^{[1
]}

Schroder, Martin ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Nottingham, Fac Engn, Energy & Sustainabil Res Div, Nottingham NG7 2RD, England

[3] Rutherford Appleton Lab, ISIS Facil, STFC, Didcot OX11 0QX, Oxon, England

[4] Gen Motors LLC, Chem Sci & Mat Syst Lab, Warren, MI 48090 USA

[5] Diamond Light Source, Didcot OX11 0DE, Oxon, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

HIGH-SURFACE-AREA; HYDROGEN-STORAGE; COORDINATION-FRAMEWORK; SORPTION; SITES; ENHANCEMENT; SPILLOVER; CATALYST; DENSITY; LITHIUM;

D O I：

10.1021/ja1001407

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neutron powder diffraction experiments on D-2-loaded NOTT-112 reveal that the axial sites of exposed Cu(II) ions in the smallest cuboctahedral cages are the first, strongest binding sites for D-2 leading to an overall discrimination between the two types of exposed Cu(II) sites at the paddlewheel nodes. Thus, the Cu(II) centers within the cuboctahedral cage are the first sites of D-2 binding with a Cu-D-2 distance of 2.23(1) angstrom.

引用

页码：4092 / +

页数：5

共 52 条

[21] Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101 [J].

Latroche, Michel ;

Surble, Suzy ;

Serre, Christian ;

Mellot-Draznieks, Caroline ;

Llewellyn, Philip L. ;

Lee, Jin-Ho ;

Chang, Jong-San ;

Jhung, Sung Hwa ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8227-8231

[22] Significantly enhanced hydrogen storage in metal-organic frameworks via spillover [J].

Li, YW ;

Yang, RT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) :726-727

[23] Hydrogen storage in metal-organic frameworks [J].

Lin, Xiang ;

Jia, Junhua ;

Hubberstey, Peter ;

Schroeder, Martin ;

Champness, Neil R. .

CRYSTENGCOMM, 2007, 9 (06) :438-448

[24] High H2 adsorption by coordination-framework materials [J].

Lin, Xiang ;

Jia, Junhua ;

Zhao, Xuebo ;

Thomas, K. Mark ;

Blake, Alexander J. ;

Walker, Gavin S. ;

Champness, Neil R. ;

Hubberstey, Peter ;

Schroeder, Martin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (44) :7358-7364

[25] High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites [J].

Lin, Xiang ;

Telepeni, Irvin ;

Blake, Alexander J. ;

Dailly, Anne ;

Brown, Craig M. ;

Simmons, Jason M. ;

Zoppi, Marco ;

Walker, Gavin S. ;

Thomas, K. Mark ;

Mays, Timothy J. ;

Hubberstey, Peter ;

Champness, Neil R. ;

Schroeder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) :2159-2171

[26] Inelastic neutron scattering of H2 adsorbed in HKUST-1 [J].

Liu, Y. ;

Brown, C. M. ;

Neumann, D. A. ;

Peterson, V. K. ;

Kepert, C. J. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 446 :385-388

[27] Increasing the density of adsorbed hydrogen with coordinatively unsaturated metal centers in metal-organic frameworks [J].

Liu, Yun ;

Kabbour, Houria ;

Brown, Craig M. ;

Neumann, Dan A. ;

Ahn, Channing C. .

LANGMUIR, 2008, 24 (09) :4772-4777

[28] Post-Synthesis Alkoxide Formation Within Metal-Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions [J].

Mulfort, Karen L. ;

Farha, Omar K. ;

Stern, Charlotte L. ;

Sarjeant, Amy A. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3866-+

[29] Hydrogen storage in metal-organic frameworks [J].

Murray, Leslie J. ;

Dinca, Mircea ;

Long, Jeffrey R. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1294-1314

[30] Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks [J].

Nouar, Farid ;

Eubank, Jarrod F. ;

Bousquet, Till ;

Wojtas, Lukasz ;

Zaworotko, Michael J. ;

Eddaoudi, Mohamed .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :1833-+

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