Aromatic δ-peptides

被引：269

作者：

Jiang, H

Léger, JM

Huc, I

机构：

[1] Inst Europeen Chim & Biol, F-33607 Pessac, France

[2] Lab Pharmacochim, F-33076 Bordeaux, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 12期

关键词：

D O I：

10.1021/ja029887k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oligoamides of 8-amino-2-carboxy-quinoline adopt a very stable helical conformation characterized in solution by 1H NMR and in the solid state by single-crystal X-ray diffraction. The helix comprises only 2.5 units per turn, which represents the highest curvature achieved by aromatic oligoamides until now. Monomers possessing alkoxy substituents in position 4 are easily available from 2-nitroaniline and dimethyl acetylenedicarboxylate. Copyright © 2003 American Chemical Society.

引用

页码：3448 / 3449

页数：2

共 23 条

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