Iron hydroxyl phosphate microspheres: Microwave-solvothermal ionic liquid synthesis, morphology control, and photoluminescent properties

被引：16

作者：

Cao, Shao-Wen ^{[1
]}

Zhu, Ying-Jie ^{[1
]}

Cui, Jing-Biao ^{[2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

[2] Univ Arkansas, Dept Phys & Astron, Little Rock, AR 72204 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Ionic liquid; Iron hydroxyl phosphate; Microwave; Nanostructures; Photoluminescence; IRON(III) PHOSPHATES; CRYSTAL-STRUCTURE; HOLLOW SPHERES; PHASE; NANOPARTICLES; TRANSITION; LAYER;

D O I：

10.1016/j.jssc.2010.05.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A variety of iron hydroxyl phosphate (NH4Fe2(PO4)(2)OH center dot 2H(2)O) nanostructures such as solid microspheres, microspheres with the core in the hollow shell, and double-shelled hollow microspheres were synthesized by a simple one-step microwave-solvothermal ionic liquid method. The effects of the experimental parameters on the morphology and crystal phase of the resultant materials were investigated. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres and the underlying mechanisms were discussed. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：1704 / 1709

页数：6

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