High resolution liquid NMR and magic angle spinning

被引：5

作者：

Delepierre, M ^{[1
]}

机构：

[1] Inst Pasteur, CNRS, URA 1129, Lab RMN, F-75724 Paris 15, France

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1998年 / 95卷 / 02期

关键词：

high resolution; magic angle spinning; small volume liquid NMR;

D O I：

10.1051/jcp:1998128

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Magic angle spinning (MAS) has since long been proven powerful in the studies of heterogeneous samples such as powdered solids, compartmentalized liquid samples, or heterogeneous solid-liquid mixtures. Recently it has been shown that higher resolution could be achieved if high-resolution magnetic-susceptibility-matching probe (Nano.nmr probe) technology was used in conjunction to MAS, In this paper we illustrate the possibilities of generating high resolution spectra of liquid using the Nano.nmr probe for the study of macromolecules in solution.

引用

页码：235 / 240

页数：6

共 13 条

[1] CYLINDRICAL DEMAGNETIZATION FIELDS AND MICROPROBE DESIGN IN HIGH-RESOLUTION NMR [J].

BARBARA, TM .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1994, 109 (02) :265-269

[2] A novel potassium channel blocking toxin from the scorpion Pandinus imperator: A H-1 NMR analysis using a nano-NMR probe [J].

Delepierre, M ;

ProchnickaChalufour, A ;

Possani, LD .

BIOCHEMISTRY, 1997, 36 (09) :2649-2658

[3] THE TIME AVERAGE MAGNETIC FIELD AT THE NUCLEUS IN NUCLEAR MAGNETIC RESONANCE EXPERIMENTS [J].

DICKINSON, WC .

PHYSICAL REVIEW, 1951, 81 (05) :717-731

[4] HIGH-RESOLUTION H-1-NMR IN SOLID-PHASE ORGANIC-SYNTHESIS [J].

FITCH, WL ;

DETRE, G ;

HOLMES, CP ;

SHOOLERY, JN ;

KEIFER, PA .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (26) :7955-7956

[5] MAGIC-ANGLE SAMPLE SPINNING OF LIQUIDS [J].

GARROWAY, AN .

JOURNAL OF MAGNETIC RESONANCE, 1982, 49 (01) :168-171

[6] SIGNAL-TO-NOISE RATIO OF NUCLEAR MAGNETIC-RESONANCE EXPERIMENT [J].

HOULT, DI ;

RICHARDS, RE .

JOURNAL OF MAGNETIC RESONANCE, 1976, 24 (01) :71-85

[7] A comparison of NMR spectra obtained for solid-phase-synthesis resins using conventional high-resolution, magic-angle-spinning, and high-resolution magic-angle-spinning probes [J].

Keifer, PA ;

Baltusis, L ;

Rice, DM ;

Tymiak, AA ;

Shoolery, JN .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1996, 119 (01) :65-75

[8] IDENTIFICATION OF A NOVEL GLYCOSAMINOGLYCAN CORE-LIKE MOLECULE .1. 500 MHZ H-1-NMR ANALYSIS USING A NANO-NMR PROBE INDICATES THE PRESENCE OF A TERMINAL ALPHA-GALNAC RESIDUE CAPPING 4-METHYLUMBELLIFERYL-BETA-D-XYLOSIDES [J].

MANZI, A ;

SALIMATH, PV ;

SPIRO, RC ;

KEIFER, PA ;

FREEZE, HH .

JOURNAL OF BIOLOGICAL CHEMISTRY, 1995, 270 (16) :9154-9163

[9] EFFECT OF DEMAGNETIZATION ON MAGNETIC-RESONANCE LINE-SHAPES IN BULK SAMPLES - APPLICATION TO TUNGSTEN [J].

MOZURKEWICH, G ;

RINGERMACHER, HI ;

BOLEF, DI .

PHYSICAL REVIEW B, 1979, 20 (01) :33-38

[10] HIGH-RESOLUTION MICROCOIL H-1-NMR FOR MASS-LIMITED, NANOLITER-VOLUME SAMPLES [J].

OLSON, DL ;

PECK, TL ;

WEBB, AG ;

MAGIN, RL ;

SWEEDLER, JV .

SCIENCE, 1995, 270 (5244) :1967-1970

← 1 2 →