Living polymerization of 1-hexene due to an extra donor arm on a novel amine bis(phenolate) titanium catalyst

被引：75

作者：

Tshuva, EY

Goldberg, I

Kol, M ^{[1
]}

Goldschmidt, Z

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 11期

基金：

以色列科学基金会;

关键词：

phenolate ligands; titanium complexes; living polymerization;

D O I：

10.1016/S1387-7003(00)00151-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two amine bis(phenolate) titanium dibenzyl complexes were synthesized in one-pot reactions starting from the ligand precursors and titanium tetra(isopropoxide). The catalyst derived from a ligand having an extra donor on a side arm leads to Living polymerization of l-hexene at room temperature, whereas the one derived from a Ligand lacking it, leads to low molecular weight poly(l-hexene) with PDI values of around 2.0. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：611 / 614

页数：4

共 27 条

[1] Synthesis of group 4 complexes that contain the tridentate diamido/donor ligands [(ArylNCH2CH2)2O]2- and zirconium complexes that contain [(ArylNCH2CH2)2S]2- and an evaluation of their activity for the polymerization of 1-hexene [J].