Rh(I)-catalyzed addition of alkenylzirconocene chlorides to aldimine derivatives

被引：41

作者：

Kakuuchi, A ^{[1
]}

Taguchi, T ^{[1
]}

Hanzawa, Y ^{[1
]}

机构：

[1] Tokyo Univ Pharm & Life Sci, Sch Pharm, Tokyo 1920392, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 05期

关键词：

alkenylation; alkenylzirconocene chloride; aldimine; rhodium catalyst;

D O I：

10.1016/S0040-4039(02)02767-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[RhCl(COD)](2) (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt)(2) and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition reactions of alkenylzirconocene chloride complexes to aldimine derivatives. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：923 / 926

页数：4

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