Carbon-nitrogen bond-forming reactions of palladacycles with hypervalent iodine reagents

被引：121

作者：

Dick, Allison R. ^{[1
]}

Remy, Matthew S. ^{[1
]}

Kampf, Jeff W. ^{[1
]}

Sanford, Melanie S. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 06期

关键词：

D O I：

10.1021/om061052l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(II) complexes containing bidentate cyclometalated C similar to N chelating ligands are shown to react with PhINTs at room temperature to insert "NTs" into the Pd-C bond. This "NTs" insertion reaction has been applied to palladacyclic complexes of azobenzene, benzo[h]quinoline, and 8-ethylquinoline. The newly aminated organic ligands can be liberated from the metal center by protonolysis with trifluoroacetic acid or HCl.

引用

页码：1365 / 1370

页数：6

共 56 条

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