Does the local built-in potential on grain boundaries of Cu(In,Ga)Se2 thin films benefit photovoltaic performance of the device?

被引:133
作者
Jiang, CS [1 ]
Noufi, R [1 ]
Ramanathan, K [1 ]
AbuShama, JA [1 ]
Moutinho, HR [1 ]
Al-Jassim, MM [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
D O I
10.1063/1.1793346
中图分类号
O59 [应用物理学];
学科分类号
摘要
In a previous paper [C.-S. Jiang , Appl. Phys. Lett. 84, 3477 (2004)], we reported the existence of a local built-in potential on grain boundaries (GBs) of photovoltaic Cu(In,Ga)Se-2 (CIGS) thin films. However, whether the built-in potential benefits photovoltaic properties of the device has not been proven. Using a scanning Kelvin probe microscope, we found that, with increasing Ga content in the CIGS film, the built-in potential on the GB drops sharply in a Ga range of 28%-38%. Comparing the changes in the built-in potential, the device efficiency, and the CIGS band gap, we conclude that the built-in potential on the GB plays a significant role in the device conversion efficiency of NREL's three-stage CIGS device. (C) American Institute of Physics.
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收藏
页码:2625 / 2627
页数:3
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