Synthesis, structure, and optoelectronic properties of II-IV-V2 materials

被引:155
作者
Martinez, Aaron D. [1 ,2 ]
Fioretti, Angela N. [1 ,2 ]
Toberer, Eric S. [1 ,2 ]
Tamboli, Adele C. [1 ,2 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
[2] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA
基金
美国国家科学基金会;
关键词
HIGH-PRESSURE SYNTHESIS; CHEMICAL-VAPOR-DEPOSITION; ORDER-DISORDER TRANSITION; X-RAY-DIFFRACTION; EPITAXIAL-GROWTH; THIN-FILMS; PHYSICAL-PROPERTIES; BAND-GAP; PHOTOELECTROCHEMICAL CHARACTERIZATION; ELECTRONIC-STRUCTURE;
D O I
10.1039/c7ta00406k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
II-IV-V-2 materials offer the promise of enhanced functionality in optoelectronic devices due to their rich ternary chemistry. In this review, we consider the potential for new optoelectronic devices based on nitride, phosphide, and arsenide II-IV-V-2 materials. As ternary analogs to the III-V materials, these compounds share many of the attractive features that have made the III-Vs the basis of modern optoelectronic devices (e.g. high mobility, strong optical absorption). Control of cation order parameter in the II-IV-V-2 materials can produce significant changes in optoelectronic properties at fixed chemical composition, including decoupling band gap from lattice parameter. Recent progress has begun to resolve outstanding questions concerning the structure, dopability, and optical properties of the II-IV-V-2 materials. Remaining research challenges include growth optimization and integration into heterostructures and devices.
引用
收藏
页码:11418 / 11435
页数:18
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