Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands:: A quest for understanding

被引：800

作者：

Diez-Gonzalez, Silvia ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 5-6期

关键词：

N-heterocyclic carbenes; transition metals; metal-ligand bond; stereoelectronic; catalysis;

D O I：

10.1016/j.ccr.2006.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The latest advances in N-heterocyclic carbene-based organometallic chemistry have drawn increasing attention to this class of ancillary ligands as an attractive alternative to tertiary phosphines. Studies focusing on the fundamental steric and electronic factors characterizing this family of compounds are therefore essential for the rationalization of the activity observed for such organometallic complexes in metal-mediated organic transformations. This knowledge is also of fundamental importance in catalyst design efforts. This review intends to provide a comprehensive overview of the progress in this area. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：874 / 883

页数：10

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