[60]- and [70]Fullerenes are trifluoromethylated across 5:6-bonds

被引：27

作者：

Darwish, AD ^{[1
]}

Avent, AG ^{[1
]}

Abdul-Sada, AK ^{[1
]}

Taylor, R ^{[1
]}

机构：

[1] Univ Sussex, CPES Sch, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 12期

关键词：

D O I：

10.1039/b303496h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifluoromethylation of[60]- and [70]fullerenes occurs across both 6:6- and 5: 6- bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6: 6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60] fullerene.

引用

页码：1374 / 1375

页数：2

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