Ultralight conductive carbon-nanotube-polymer composite

被引:151
作者
Xu, Xiang-Bin [1 ]
Li, Zhong-Ming [1 ]
Shi, Lei [1 ]
Bian, Xiang-Cheng [1 ]
Xiang, Zhi-Dong [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
关键词
carbon nanotubes; conducting polymers; foams; lightweight materials; nanocomposites;
D O I
10.1002/smll.200600348
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The fabrication of a conductive carbon nanotube/polyurethane (CNT/PU) foam with a low density of 0.05g cm-3 and a conductivity of 43x10 -5Sm-1 was analyzed. This lightest conductive polymer composite has a weight-reduction rate of 96.2%. A novel density-dependent conductor-insulator transition was developed that determines the limit of the reduction in weight for a conductive composite. This density-dependent conductor-insulator transition is related to the microstructure of the low-density conductive polymer composite. The reduction in weight of the composites brought remarkable advantages for electronic devices such as aircraft, spacecraft, and automobiles. The weight reduction saved both materials and energy. Results show that the carbon-nanofiber and nanotube-filled polystyrene conductive foams have been developed for a lightweight EMI-sheilding composite.
引用
收藏
页码:408 / 411
页数:4
相关论文
共 28 条
[1]   Photomechanical actuation in polymer-nanotube composites [J].
Ahir, SV ;
Terentjev, EM .
NATURE MATERIALS, 2005, 4 (06) :491-495
[2]   Polymer nanofibers and nanotubes: Charge transport and device applications [J].
Aleshin, AN .
ADVANCED MATERIALS, 2006, 18 (01) :17-27
[3]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[4]   Very low conductivity threshold in bulk isotropic single-walled carbon nanotube-epoxy composites [J].
Bryning, MB ;
Islam, MF ;
Kikkawa, JM ;
Yodh, AG .
ADVANCED MATERIALS, 2005, 17 (09) :1186-+
[5]   Photoconductivity study of modified carbon nanotube/oxotitanium phthalocyanine composites [J].
Cao, L ;
Chen, HZ ;
Wang, M ;
Sun, JZ ;
Zhang, XB ;
Kong, FZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (35) :8971-8975
[6]   Probing electrical transport in nanomaterials: Conductivity of individual carbon nanotubes [J].
Dai, HJ ;
Wong, EW ;
Lieber, CM .
SCIENCE, 1996, 272 (5261) :523-526
[7]   Synthesis of conductive polypyrrole/polyurethane foams via a supercritical fluid process [J].
Fu, YP ;
Palo, DR ;
Erkey, C ;
Weiss, RA .
MACROMOLECULES, 1997, 30 (24) :7611-7613
[8]   Dramatic effect of dispersed carbon nanotubes on the mechanical and electroconductive properties of polymers derived from ionic liquids [J].
Fukushima, T ;
Kosaka, A ;
Yamamoto, Y ;
Aimiya, T ;
Notazawa, S ;
Takigawa, T ;
Inabe, T ;
Aida, T .
SMALL, 2006, 2 (04) :554-560
[9]   COMPOSITION AND ELECTRICAL-PROPERTIES OF AU-AL2O3 CERMET THIN-FILMS - A CRITICAL-STUDY [J].
GADENNE, M ;
GADENNE, P ;
MARTIN, JC ;
SELLA, C .
THIN SOLID FILMS, 1992, 221 (1-2) :183-190
[10]   Achieving individual-nanotube dispersion at high loading in single-walled carbon nanotube composites [J].
Graff, RA ;
Swanson, JP ;
Barone, PW ;
Baik, S ;
Heller, DA ;
Strano, MS .
ADVANCED MATERIALS, 2005, 17 (08) :980-+