Synthesis and luminescence behavior of rhenium(I) triynyl complexes.: X-ray crystal structures of [Re(CO)3(tBu2bpy)(CC-CC-CCPh)] and [Re(CO)3(Me2bpy)(CC-CC-CCSiMe3)]

被引:58
作者
Yam, VWW [1 ]
Chong, SHF [1 ]
Ko, CC [1 ]
Cheung, KK [1 ]
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
关键词
D O I
10.1021/om000725b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Luminescent rhenium(I) triynyl complexes [Re(CO)(3)((t)Bu(2)bpy)(C=C-C=C-C=CPh)] 1, [Re(CO)(3)((t)Bu(2)bpy)(C=C - C=C-C=CSiMe3)] 2, and [Re(CO)(3)(Me(2)bpy)(C=C- C=C-C= CSiMe3)] 3, were synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structures of 1 and 3 have also been determined. A comparison study of their emission properties to that of their mono- and diynyl analogues was made and their emission origin suggested and supported by EHMO studies.
引用
收藏
页码:5092 / 5097
页数:6
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