Unusual nickel-mediated C-S cleavage of alkyl and aryl sulfoxides

被引：64

作者：

Schaub, Thomas ^{[1
]}

Backes, Marc ^{[1
]}

Radius, Udo ^{[1
]}

机构：

[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 20期

关键词：

D O I：

10.1039/b618632g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of transition metal mediated C-S cleavage of sulfoxides containing sp(2)- and sp(3)-hybridized carbon bonds attached to the sulfur atom and the first example of a structurally characterized complex featuring an oxygen-bound sulfinyl ligand are presented.

引用

页码：2037 / 2039

页数：3

共 51 条

[41] Nickel(0) complexes of N-alkyl-substituted N-heterocyclic carbenes and their use in the catalytic carbon-carbon bond activation of biphenylene [J].

Schaub, Thomas ;

Backes, Marc ;

Radius, Udo .

ORGANOMETALLICS, 2006, 25 (17) :4196-4206

[42]

Seebach D, 1997, B SOC CHIM FR, V134, P315

[43] ALKYL AND HYDRIDO PHENOXO COMPLEXES OF NICKEL(II), PALLADIUM(II), AND PLATINUM(II) - HYDRIDO AMIDO COMPLEXES OF PALLADIUM [J].

SELIGSON, AL ;

COWAN, RL ;

TROGLER, WC .

INORGANIC CHEMISTRY, 1991, 30 (18) :3371-3381

[44]

Sheldrick G.M., 1993, PROGRAM CRYSTAL STRU

[45] SYNTHESIS AND STRUCTURE OF THE S-METHYLSULFENATO BRIDGED CATION [ETA-6-MEC6H5)MO(MU-S(O)ME)MU-SME)3MON(ETA-6-MEC6H5)]2+ [J].

SILVERTHORN, WE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 184 (02) :C25-C27

[46] Synthesis and crystal structure of a unique and homochiral N,S-bonded N,N′-bis(tert-butanesulfinyl)amidinate rhodium(I) complex [J].

Souers, AJ ;

Owens, TD ;

Oliver, AG ;

Hollander, FJ ;

Ellman, JA .

INORGANIC CHEMISTRY, 2001, 40 (20) :5299-+

[47] METALLOSULFOXIDES AND METALLOSULFONES - SULFUR OXYGENATES OF [1,5-BIS(2-MERCAPTOETHYL)-1,5-DIAZACYCLOOCTANATO]PALLADIUM(II) [J].

TUNTULANI, T ;

MUSIE, G ;

REIBENSPIES, JH ;

DARENSBOURG, MY .

INORGANIC CHEMISTRY, 1995, 34 (25) :6279-6286

[48] METAL-COMPLEXES OF FUNCTIONALIZED SULFUR-CONTAINING LIGANDS .3. REACTIONS OF (PH3P)2PT(ETA-2-C2H4) WITH ACYCLIC-THIOSULFINATES AND CYCLIC-THIOSULFINATES - PLATINUM(II)-THIOLATO COMPLEXES WITH SULFENATO LIGANDS - CRYSTAL-STRUCTURE DETERMINATION OF (4-SULFIDO-1-BUTANESULFENATO-S,S')BIS(TRIPHENYLPHOSPHANE)PLATINUM(II) (PH3P)2PT-S(O)-[CH2]4-S [J].

WEIGAND, W ;

BOSL, G ;

ROBL, C ;

AMREIN, W .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (05) :1047-1051

[49] NICKEL-INDUCED CONVERSION OF CARBON-SULFUR INTO CARBON-CARBON BONDS - ONE-STEP TRANSFORMATIONS OF ENOL SULFIDES INTO OLEFINS AND BENZENETHIOL DERIVATIVES INTO ALKYLARENES AND BIARYLS [J].

WENKERT, E ;

FERREIRA, TW ;

MICHELOTTI, EL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (14) :637-638

[50] Diastereoselective oxidative addition of cyclic thiosulfinates to platinum(0) compounds:: chiral platinum(II) complexes with sulfenato ligands -: Crystal structures of S(O)-CH2-CH(OAc)-CH(OAc)-CH2-S and dppePt[S(O)-(CH2)4-S] Part 16.: Metal complexes of functionalized sulfur-containing ligands [J].

Wünsch, R ;

Bosl, G ;

Robl, C ;

Weigand, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 621 (1-2) :352-358

← 1 2 3 4 5 6 →