Synthesis of cationic cyclooctatetraene uranium complexes by protonolysis of borohydride precursors: The first cationic organometallic borohydride and the first organometallic dication of an f element

被引：20

作者：

Cendrowski-Guillaume, SM ^{[1
]}

Lance, M ^{[1
]}

Nierlich, M ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA Saclay, CNRS URA 331, DSM, DRECAM,Serv Chim Mol, F-91191 Gif Sur Yvette, France

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 16期

关键词：

D O I：

10.1021/om000155f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (COT)U(BH4)(2)(THF) (COT = eta- C8H8, THF = tetrahydrofuran) with NEt3HBPh4 afforded [(COT)U(BH4)(THF)(2)][BPh4] (1), which further reacted with the ammonium salt in, the presence of HMPA to give [(COT) U(HMPA)(3)][BPh4](2) (2); the crystal structure of a pyridine solvate of 2 has been determined.

引用

页码：3257 / 3259

页数：3

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