Guest-binding properties of functionally porous crystal based on metal complex of p-tert-butylthiacalix[6]arene

被引：23

作者：

Endo, K

Kondo, Y

Aoyama, Y

Hamada, F

机构：

[1] Akita Univ, Fac Engn & Resource Sci, Dept Mat Proc Engn & Appl Chem Environm, Akita 0108502, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 07期

关键词：

crystal structure; calixarenes; porous crystal; guest binding; metal complex; COORDINATION; NETWORK; CATALYSIS; DESIGN;

D O I：

10.1016/S0040-4039(02)02873-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A potassium salt of p-tert-butylthiacalix[6]arene shows highly-extensive coordination nature to give rise to zeolitic crystal which has huge cavity with the widest span of ca. 19 Angstrom and is capable of crystalline phase guest-addition and -removal. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1355 / 1358

页数：4

共 23 条

[21] Cation-π interactions between potassium ions and aromatic rings.: Crystal structures of three potassium complexes of calix[6]arene [J].

Murayama, K ;

Aoki, K .

INORGANICA CHIMICA ACTA, 1998, 281 (01) :36-42

[22]

PIVOVAR AM, 2001, J AM CHEM SOC, V123, P4421

[23] Immobilization of a soluble metal complex in an organic network. Remarkable catalytic performance of a porous dialkoxyzirconium polyphenoxide as a functional organic zeolite analogue [J].

Sawaki, T ;

Aoyama, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (20) :4793-4798

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