Guest-binding properties of functionally porous crystal based on metal complex of p-tert-butylthiacalix[6]arene

被引：23

作者：

Endo, K

Kondo, Y

Aoyama, Y

Hamada, F

机构：

[1] Akita Univ, Fac Engn & Resource Sci, Dept Mat Proc Engn & Appl Chem Environm, Akita 0108502, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 07期

关键词：

crystal structure; calixarenes; porous crystal; guest binding; metal complex; COORDINATION; NETWORK; CATALYSIS; DESIGN;

D O I：

10.1016/S0040-4039(02)02873-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A potassium salt of p-tert-butylthiacalix[6]arene shows highly-extensive coordination nature to give rise to zeolitic crystal which has huge cavity with the widest span of ca. 19 Angstrom and is capable of crystalline phase guest-addition and -removal. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：1355 / 1358

页数：4

相关论文

共 23 条

[11]

Gutsche C.D., 1998, CALIXARENES REVISITE

[12] Coordination of epithio groups of p-tert-butylthiacalix[4]arene in a Zn2+ complex studied by X-ray crystallography [J].

Iki, N ;

Morohashi, N ;

Kabuto, C ;

Miyano, S .

CHEMISTRY LETTERS, 1999, (03) :219-220

[13] Can thiacalixarene surpass calixarene? [J].

Iki, N ;

Miyano, S .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 41 (1-4) :99-105

[14] Crystal structure and inclusion property of p-tert-butylthiacalix [6]arene [J].

Iki, N ;

Morohashi, N ;

Suzuki, T ;

Ogawa, S ;

Aono, M ;

Kabuto, C ;

Kumagai, H ;

Takeya, H ;

Miyanari, S ;

Miyano, S .

TETRAHEDRON LETTERS, 2000, 41 (15) :2587-2590

[15] Synthesis, structure, and ferromagnetic behavior of decacopper(II) cluster complex supported by hexaanionic p-tert-butylthiacalix[6]arene [J].

Kajiwara, T ;

Kon, N ;

Yokozawa, S ;

Ito, T ;

Iki, N ;

Miyano, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) :11274-11275

[16]

Kitaura R, 2002, ANGEW CHEM INT EDIT, V41, P133, DOI 10.1002/1521-3773(20020104)41:1<133::AID-ANIE133>3.0.CO

[17]

2-R

[18] Design and structural analysis of interpenetrated 3-D co-ordination networks formed by self-assembly using tetrapyridinocyclophane and silver cations [J].

Klein, C ;

Graf, E ;

Hosseini, MW ;

De Cian, A .

NEW JOURNAL OF CHEMISTRY, 2001, 25 (02) :207-209

[19]

Leverd PC, 1998, EUR J INORG CHEM, P1859

[20] Open dimeric and capped polymeric container molecules:: calixarene and resorcinarene complexes of AgI co-ordinated by participation of the upper-rim carbon atoms [J].

Munakata, M ;

Wu, LP ;

Kuroda-Sowa, T ;

Maekawa, M ;

Suenaga, Y ;

Sugimoto, K ;

Ino, I .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (03) :373-378