Calcium-catalyzed intermolecular hydrophosphination

被引：174

作者：

Crimmin, Mark R.

Barrett, Anthony G. M.

Hill, Michael S.

Hitchcock, Peter B.

Procopiou, Panayiotis A.

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

[3] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 12期

关键词：

D O I：

10.1021/om070200k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The beta-diketiminato complex [{HC(C(Me)(2)N-2,6-(Pr2C6H3)-Pr-i)(2)}Ca{N(SiMe3)(2)}(THF)] effects intermolecular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.

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页码：2953 / 2956

页数：4

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