First asymmetric SMI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds

被引:30
作者
Chavarot, M
Rivard, M
Rose-Munch, F
Rose, E
Py, S
机构
[1] Univ Paris 06, Chim Organ Lab, UMR 7611, F-75252 Paris 05, France
[2] Univ Grenoble 1, LEDSS, UMR 5616, F-38041 Grenoble 9, France
关键词
D O I
10.1039/b405406g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The SmI2-induced cross-coupling of Cr(CO)(3)-complexed nitrones with carbonyl compounds is described. This highly chemo- and diastereoselective reaction affords enantiopure beta-amino alcohol complexes in excellent yields.
引用
收藏
页码:2330 / 2331
页数:2
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