Isoreticular homochiral porous metal-organic structures with tunable pore sizes

被引:151
作者
Dybtsev, Danil N.
Yutkin, Maxim P.
Peresypkina, Eugenia V.
Virovets, Alexander V.
Serre, Christian
Ferey, Gerard
Fedin, Vladimir P. [1 ]
机构
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Univ Versailles, Inst Lavoisier, F-78000 Versailles, France
关键词
D O I
10.1021/ic7009226
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chiral-layered building motifs of zinc(ll) camphorate are linked through linear N-donor ligands, forming series of three-dimensional isoreticular porous homochiral frameworks. The lengths of these linear ligands control the pore sizes and free accessible volumes of the homochiral metal-organic structures.
引用
收藏
页码:6843 / 6845
页数:3
相关论文
共 29 条
[1]   Permanent microporosity and enantioselective sorption in a chiral open framework [J].
Bradshaw, D ;
Prior, TJ ;
Cussen, EJ ;
Claridge, JB ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114
[2]   Hydrogen adsorption in an interpenetrated dynamic metal-organic framework [J].
Chen, Banglin ;
Ma, Shengqian ;
Zapata, Fatima ;
Lobkovsky, Emil B. ;
Yang, Jun .
INORGANIC CHEMISTRY, 2006, 45 (15) :5718-5720
[3]   A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].
Chen, BL ;
Liang, CD ;
Yang, J ;
Contreras, DS ;
Clancy, YL ;
Lobkovsky, EB ;
Yaghi, OM ;
Dai, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393
[4]   A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].
Cho, So-Hye ;
Ma, Baoqing ;
Nguyen, SonBinh T. ;
Hupp, Joseph T. ;
Albrecht-Schmitt, Thomas E. .
CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565
[5]   Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials [J].
Chun, H ;
Dybtsev, DN ;
Kim, H ;
Kim, K .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (12) :3521-3529
[6]   Supramolecular arrays based on dimetal building units [J].
Cotton, FA ;
Lin, C ;
Murillo, CA .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (10) :759-771
[7]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[8]   A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].
Dybtsev, DN ;
Nuzhdin, AL ;
Chun, H ;
Bryliakov, KP ;
Talsi, EP ;
Fedin, VP ;
Kim, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920
[9]   Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].
Dybtsev, DN ;
Chun, H ;
Yoon, SH ;
Kim, D ;
Kim, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33
[10]   Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior [J].
Dybtsev, DN ;
Chun, H ;
Kim, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :5033-5036